Syntheses and Structures of Zinc Bis(iminodiphenylphosphorane)methanide Complexes

Reactions of bis(phosphinimino)methanes H2C(PPh2NR)2 [R = SiMe3 (L1H), Ph (L2H), 2,6‐iPr2‐C6H3 (DIPP) (L3H)] with ZnR2 (R = Me, Et) yielded the corresponding bis(phosphinimino)methanide zinc complexes LZnMe [L2 (1), L3 (2)] and LZnEt [L1 (3), L2 (4), and L3 (5)]. Complexes 15 were characterized by heteronuclear NMR (1H, 13C, 31P) and IR spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction.


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