Non-innocence of β-diketiminato ligands

The homoleptic thio-β-ketiminate zinc complex [MesNC(Me)CH{C(Me)NMes}S]2Zn (1) was obtained from reactions of elemental sulfur with the β-diketiminato zinc complexes [CH{C(Me)NMes}2]ZnMe, [CH{C(Me)NMes}2]2Zn2 and [[CH{C(Me)NMes}2]Zn-TePh]2. 1 and the byproducts were characterized by multinuclear NMR (1H, 13C, 125Te) and IR spectroscopy, elemental analyses as well as by single crystal X-ray diffraction.

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