Non-innocence of β-diketiminato ligands

The homoleptic thio-β-ketiminate zinc complex [MesNC(Me)CH{C(Me)NMes}S]2Zn (1) was obtained from reactions of elemental sulfur with the β-diketiminato zinc complexes [CH{C(Me)NMes}2]ZnMe, [CH{C(Me)NMes}2]2Zn2 and [[CH{C(Me)NMes}2]Zn-TePh]2. 1 and the byproducts were characterized by multinuclear NMR (1H, 13C, 125Te) and IR spectroscopy, elemental analyses as well as by single crystal X-ray diffraction.

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Date Issued:
25.11.2020
URN:
urn:nbn:de:hbz:464-20201125-110115-9
DOI:
10.1016/j.jorganchem.2015.02.028
Language:
English
Type of Resource:
Text
Keywords:
Zinc; β-diketiminate; sulfur
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Info on primary publication:

This is the Authors Accepted Manuscript of an article published in: Journal of Organometallic Chemistry, 783 (2015), 92-95. Available online 25 February 2015.

The final version may be found at: https://doi.org/10.1016/j.jorganchem.2015.02.028

version identification:
Authors Accepted Manuscript

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