Reactions of a Zn(I) complex with group 14 azides – Formation of zinc azide and zinc hexazene complexes

Gondzik, Sebastian GND; Schulz, Stephan GND; Bläser, Dieter; Wölper, Christoph GND; Haack, Rebekka LSF; Jansen, Georg LSF

Two zinc hexazene complexes L2Zn2(μ-1,6-R2-N6) (L = HC[C(Me)N(2,4,6-Me3C6H2)]2; R = Ph (3), Dipp = 2,6-i-Pr2C6H3 (4)), were synthesized by reaction of the Zn(I) complex L2Zn2 (1) with phenyl azide and 2,6-diisopropylphenyl azide, respectively. 3 represents the second structurally characterized transition metal hexazene complex. In contrast, reactions of 1 with Me3MN3 (M = Si, Sn) yielded the azido complex [LZn(μ-N3)]2 (2) and Me3M-MMe3.

Dedicated to Prof. Peter Jutzi on the occasion of his 75th birthday.

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Gondzik, S., Schulz, S., Bläser, D., Wölper, C., Haack, R., Jansen, G., 2020. Reactions of a Zn(I) complex with group 14 azides – Formation of zinc azide and zinc hexazene complexes. https://doi.org/10.1039/C3CC47687A
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