Reactions of a β-diketiminate zinc hydride complex with heterocumulenes.

Schulz, Stephan GND; Eisenmann, Tamara GND; Schmidt, Sarah GND; Bläser, Dieter; Westphal, Ulrich; Boese, Roland GND

The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO(2), C(Ni-Pr)(2) and t-BuNCO at ambient temperature with insertion into the Zn-H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes.

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Schulz, S., Eisenmann, T., Schmidt, S., Bläser, D., Westphal, U., Boese, R., 2020. Reactions of a β-diketiminate zinc hydride complex with heterocumulenes. https://doi.org/10.1039/C0CC01329C
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