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  • Reactions of a β-diketiminate zinc hydride complex with heterocumulenes.

Reactions of a β-diketiminate zinc hydride complex with heterocumulenes.

The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO(2), C(Ni-Pr)(2) and t-BuNCO at ambient temperature with insertion into the Zn-H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes.

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Date Issued:
04.11.2020
URN:
urn:nbn:de:hbz:464-20201104-090808-9
DOI:
10.1039/C0CC01329C
Other identifier (pubmed):
20820504
Language:
English
Type of Resource:
Text
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Info on primary publication:

Accepted Manuscript. The final article was published in: Chemical Communications, 2010, 46, 7226-7228 and is available at: https://doi.org/10.1039/C0CC01329C

First published:1 Sep 2010

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