Synthesis and Characterization of β-Diketiminate Zinc Complexes

Reactions of the monomeric β-diketiminate zinc complex (Mes)NacNacZnMe
(MesNacNac = {[2,6-(2,4,6-Me3-C6H2)N(Me)C)]2CH}) with ROH (R = Me, Et, i-Pr) yielded the corresponding zinc alcoholates [(Mes)NacNacZnOR]2 (R = Me 1, Et 2, i-Pr 3). In addition, the reaction of (Mes)NacNacZnCl with various reducing agents such as K-graphite, K, or Na gave the Zn(II) complex [(Mes)NacNac]2Zn 4. 1 - 4 were characterized by elemental analyses, mass and multinuclear (1H, 13C{1H}) NMR spectroscopy (1H, 13C), and by single crystal Xray analysis.

Dedicated to Prof. Gerd Meyer on the occasion of his 60th birthday.

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Einordnung

Datum der Veröffentlichung:
30.10.2020
URN:
urn:nbn:de:hbz:464-20201030-102545-9
DOI:
10.1002/zaac.200801382
Sprache:
Englisch
Ressourcentyp:
Text
Schlagwörter:
Zinc; β-Diketiminate; X-Ray Structure
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This is the peer reviewed version of the following article: Z. Anorg. Allg . Chem. 2009, 635, 995-1000, which has been published in final form at:

https://doi.org/10.1002/zaac.200801382

Version of Record online: 18 May 2009

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This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Versionskennzeichen:
Authors Accepted Manuscript.

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