Insights into Molecular Beryllium–Silicon Bonds

Naglav, Dominik LSF; Tobey, Briac LSF; Dzialkowski, Kevin LSF; Jansen, Georg LSF; Wölper, Christoph LSF; Schulz, Stephan LSF

We present the synthesis of two silyl beryllium halides HypSiBeX∙(thf) (HypSi = Si(SiMe3)3, X = Cl 2a, I 4a) and the molecular structure of 2a as determined by single crystal X-ray diffraction. Compounds 2a and 4a were characterized via multi-nuclear NMR spectroscopy (1H, 9Be, 13C, 29Si), and the bonding situation was further investigated using quantum chemical calculations (with the addition of further halides X = F 1b, Cl 2b, Br 3b, I 4b). The nature of the beryllium silicon bond in the context of these compounds is highlighted and discussed.

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Naglav, D., Tobey, B., Dzialkowski, K., Jansen, G., Wölper, C., Schulz, S., 2018. Insights into Molecular Beryllium–Silicon Bonds. https://doi.org/10.3390/inorganics5020022
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