Total Synthesis of Resveratrone and iso-Resveratrone

Fritsch, Stefan; Aldemir, Nazli; Balszuweit, Jan; Bojaryn, Kevin; Voskuhl, Jens; Hirschhäuser, Christoph

doi:10.1002/open.202200098

Artikel / Aufsatz Do., 30. Juni. 2022 CC BY 4.0

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Total Synthesis of Resveratrone and iso-Resveratrone

Fritsch, Stefan; Aldemir, Nazli ; Balszuweit, Jan ; Bojaryn, Kevin ; Voskuhl, Jens ; Hirschhäuser, Christoph

The first total synthesis of resveratrone and iso-resveratrone based on an epoxide olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated epoxide into a boronic ester and subsequent syn-elimination. Resveratrone has been described to have remarkable photophysical properties, including two-photon absorption. Therefore, an azide derivative has been prepared to allow for use as a biological label.

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Datum der Veröffentlichung:: 30.06.2022
URN:: urn:nbn:de:hbz:465-20231120-150119-8
DOI:: 10.1002/open.202200098
Sprache:: Englisch
Ressourcentyp:: Text
Kollektion:: E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:: 540 Chemie
Einrichtung:: Fakultät für Chemie, Organische Chemie
Einrichtung:: Forschungszentren, Center for Nanointegration Duisburg-Essen (CENIDE)
Förderung:: The publication of this article was supported by the Publication Fund of the University of Duisburg-Essen.
Informationen zur Erstveröffentlichung:: S. Fritsch, N. Aldemir, J. Balszuweit, K. Bojaryn, J. Voskuhl, C. Hirschhäuser, Total Synthesis of Resveratrone and iso-Resveratrone. ChemistryOpen 2022, 11, e202200098.https://doi.org/10.1002/open.202200098

First published: 30 June 2022
Versionskennzeichen:: Version of Record / Verlagsversion