Total Synthesis of Resveratrone and iso-Resveratrone

The first total synthesis of resveratrone and iso-resveratrone based on an epoxide olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated epoxide into a boronic ester and subsequent syn-elimination. Resveratrone has been described to have remarkable photophysical properties, including two-photon absorption. Therefore, an azide derivative has been prepared to allow for use as a biological label.

Preview

Category

Date Issued:
30.06.2022
URN:
urn:nbn:de:hbz:465-20231120-150119-8
DOI:
10.1002/open.202200098
Language:
English
Type of Resource:
Text
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Organische Chemie
Hosting institution:
Scientific institutes, Center for Nanointegration Duisburg-Essen (CENIDE)
funding:

The publication of this article was supported by the Publication Fund of the University of Duisburg-Essen.

Info on primary publication:

S. Fritsch, N. Aldemir, J. Balszuweit, K. Bojaryn, J. Voskuhl, C. Hirschhäuser, Total Synthesis of Resveratrone and iso-Resveratrone. ChemistryOpen 2022, 11, e202200098.https://doi.org/10.1002/open.202200098

First published: 30 June 2022
version identification:
Version of Record / Verlagsversion

Cite

Citation style:
Could not load citation form.

Rights

License Holder:

© 2022 The Authors

Use and reproduction:
This work may be used under a
CC BY 4.0 LogoCreative Commons Attribution 4.0 License (CC BY 4.0)
.