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Synthesis and X-ray crystal structures of Ga-substituted distibenes [L(X)GaSb]2

The reactions of two equivalents of LGa {L = HC[C(Me)N(2,6‐iPr2C6H3)]2} with SbX3 (X = Br, I, OEt) proceed with elimination of LGaX2 and formation of Ga‐substituted distibenes [L(X)GaSb]2 [X = Br (1), I (2), OEt (3)]. Compounds 1 to 3 were characterized by heteronuclear NMR (1H, 13C), IR and UV/Vis spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction.

Dedicated to Prof. A. Filippou on the Occasion of his 60th Birthday.

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Einordnung

Datum der Veröffentlichung:
18.12.2020
URN:
urn:nbn:de:hbz:464-20201218-093919-7
DOI:
10.1002/zaac.201800204
Sprache:
Englisch
Ressourcentyp:
Text
Schlagwörter:
Antimony; Gallium; Multiple Bonds; X-ray Diffraction
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Einrichtung:
Forschungszentren, Center for Nanointegration Duisburg-Essen (CENIDE)
Informationen zur Erstveröffentlichung:

This is the peer reviewed version of the following article: Z. Anorg. Allg . Chem. 2018, 644, 1028-1033, which has been published in final form at:
https://doi.org/10.1002/zaac.201800204

Version of Record online: 13 July 2018

Restriktion:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Versionskennzeichen:
Authors Accepted Manuscript.

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