Synthesis and X-ray crystal structures of Ga-substituted distibenes [L(X)GaSb]2

The reactions of two equivalents of LGa {L = HC[C(Me)N(2,6‐iPr2C6H3)]2} with SbX3 (X = Br, I, OEt) proceed with elimination of LGaX2 and formation of Ga‐substituted distibenes [L(X)GaSb]2 [X = Br (1), I (2), OEt (3)]. Compounds 1 to 3 were characterized by heteronuclear NMR (1H, 13C), IR and UV/Vis spectroscopy, elemental analysis, and single‐crystal X‐ray diffraction.

Dedicated to Prof. A. Filippou on the Occasion of his 60th Birthday.


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