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Synthesis, Solid State Structure and Bonding Analysis of the first Homoleptic Beryllium Azide

[Ph4P]2[Be(N3)4] (1) and [PNP]2[Be(N3)4] (2; PNP=Ph3PNPPh3) were synthesized by reacting Be(N3)2 with [Ph4P]N3 and [PNP]N3. Compound 1 represents the first structurally characterized homoleptic beryllium azide. The electronic structure and bonding situation in the tetraazidoberyllate dianion [Be(N3)4]2− were investigated by quantum‐chemical calculations (NPA, ELF, LOL).

In memoriam Prof. K. Dehnicke.

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Einordnung

alternativ:
Synthesis, Solid‐State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide
Datum der Veröffentlichung:
10.12.2020
URN:
urn:nbn:de:hbz:464-20201210-173710-7
DOI:
10.1002/anie.201703147
Sprache:
Englisch
Ressourcentyp:
Text
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Einrichtung:
Forschungszentren, Center for Nanointegration Duisburg-Essen (CENIDE)
Informationen zur Erstveröffentlichung:

This is the peer reviewed version of the following article: Naglav, D., Tobey, B., Lyhs, B., Römer, B., Bläser, D., Wölper, C., Schulz, S.: Synthesis, Solid‐State Structure, and Bonding Analysis of a Homoleptic Beryllium Azide. Angew. Chem.Internat. Ed. 2017, 56, 8559-8563, which has been published in final form at:
https://doi.org/10.1002/anie.201703147

Version of Record online: 20 June 2017

Restriktion:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Versionskennzeichen:
Authors Accepted Manuscript.

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