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Synthesis and Structure of Bis(diphenylphosphinimino)methanide and Bis(diphenylphosphinimino)methanediide Beryllium Complexes

Reactions of BeEt2 with bis(diphenylphosphinimino)methanes H2C[PPh2NR]2 yielded the first bis(diphenylphosphinimino)methanide and bis(diphenylphosphinimino)methanediide beryllium complexes [CH(PPh2N-2,6-i-Pr2C6H3)2]BeEt (1), [C(PPh2NSiMe3)2](BeEt)2 (2), and [C(PPh2NPh)2](BeEt)2 (3), respectively. 1–3 were characterized by multinuclear NMR and IR spectroscopy as well as single-crystal X-ray diffraction.

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Datum der Veröffentlichung:
04.12.2020
URN:
urn:nbn:de:hbz:464-20201204-121650-1
DOI:
10.1021/acs.organomet.6b00380
Sprache:
Englisch
Ressourcentyp:
Text
Schlagwörter:
Beryllium; Metals; Ligands; Crystal structure; Substituents
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Organometallics 2016, 35, 14, 2378-2383, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:
https://doi.org/10.1021/acs.organomet.6b00380

Published online 7 July 2016

Versionskennzeichen:
Authors Accepted Manuscript.

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