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Alternate precursors for the synthesis of binary Sb2E3 and Bi2E3 (E = S, Se, Te) nanoparticles by hot injection method

Intramolecularly stabilized Sb(OCH2CH2NMe2)3 (1) and Bi(OCH2CH2NMe2)3 (2) readily react with (Me3Si)2S and (Et3Si)2E (E = Se, Te) at moderate temperatures (hot injection method) with elimination of the corresponding silyl ether and subsequent formation of the group 15 chalcogenides Sb2E3 and Bi2E3, which were characterized by XRD, SEM, and energy‐dispersive X‐ray spectroscopy (EDX). In addition, the solid‐state structure of 1 was determined by single‐crystal XRD.

 

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Einordnung

alternativ:
Alternative Precursors for the Synthesis of Binary Sb2E3 and Bi2E3 (E = S, Se, Te) Nanoparticles by the Hot Injection Method
Datum der Veröffentlichung:
03.12.2020
URN:
urn:nbn:de:hbz:464-20201203-173012-0
DOI:
10.1002/ejic.201600490
Sprache:
Englisch
Ressourcentyp:
Text
Schlagwörter:
Nanoparticles; Hot injection; Chalcogens; Antimony; Bismuth
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This is the peer reviewed version of the following article: Rusek, M., Wölper, C., Schulz, S.: Alternative Precursors for the Synthesis of Binary Sb2E3 and Bi2E3 (E = S, Se, Te) Nanoparticles by the Hot Injection Method. Eur. J. Inorg. Chem. 2016, 22 3673-3679, which has been published in final form at:
https://doi.org/10.1002/ejic.201600490

Version of Record online: 04 July 2016

Restriktion:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Versionskennzeichen:
Authors Accepted Manuscript.

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