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Alternate precursors for the synthesis of binary Sb2E3 and Bi2E3 (E = S, Se, Te) nanoparticles by hot injection method

Intramolecularly stabilized Sb(OCH2CH2NMe2)3 (1) and Bi(OCH2CH2NMe2)3 (2) readily react with (Me3Si)2S and (Et3Si)2E (E = Se, Te) at moderate temperatures (hot injection method) with elimination of the corresponding silyl ether and subsequent formation of the group 15 chalcogenides Sb2E3 and Bi2E3, which were characterized by XRD, SEM, and energy‐dispersive X‐ray spectroscopy (EDX). In addition, the solid‐state structure of 1 was determined by single‐crystal XRD.

 

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alternative:
Alternative Precursors for the Synthesis of Binary Sb2E3 and Bi2E3 (E = S, Se, Te) Nanoparticles by the Hot Injection Method
Date Issued:
03.12.2020
URN:
urn:nbn:de:hbz:464-20201203-173012-0
DOI:
10.1002/ejic.201600490
Language:
English
Type of Resource:
Text
Keywords:
Nanoparticles; Hot injection; Chalcogens; Antimony; Bismuth
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Info on primary publication:

This is the peer reviewed version of the following article: Rusek, M., Wölper, C., Schulz, S.: Alternative Precursors for the Synthesis of Binary Sb2E3 and Bi2E3 (E = S, Se, Te) Nanoparticles by the Hot Injection Method. Eur. J. Inorg. Chem. 2016, 22 3673-3679, which has been published in final form at:
https://doi.org/10.1002/ejic.201600490

Version of Record online: 04 July 2016

restriction:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
version identification:
Authors Accepted Manuscript.

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