Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study.

Naglav, Dominik GND; Neumann, Alexander GND; Bläser, Dieter; Wölper, Christoph GND; Haack, Rebekka LSF; Jansen, Georg LSF; Schulz, Stephan GND

The solid state structure of Be[N(SiMe3)2]2 (1) was determined by in situ crystallisation and the bonding situation investigated by quantum chemical calculations. The Be-N bond is predominantly ionic, but some evidence for the presence of a partial Be-N double bond character was found.

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Naglav, D., Neumann, A., Bläser, D., Wölper, C., Haack, R., Jansen, G., Schulz, S., 2015. Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study. https://doi.org/10.1039/C4CC09732G
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