Germane vs. digermane formation

Steiniger, Phillip GND; Bendt, Georg GND; Bläser, Dieter; Wölper, Christoph GND; Schulz, Stephan GND

Oxidative addition reactions of dialkylchalcogenanes R2E2 and [Me2Si(Nt-Bu)2]Ge 1 yielded bis(alkylchalcogeno)germanes Me2Si(Nt-Bu)2Ge(ER)2 (R = Et, E = S 2, Se 3; R = Me, E = Se 4) and digermanes [Me2Si(Nt-Bu)2Ge(EEt)]2 (E = S 5, Se 6). The reaction of 1 with Et2Te2 proceeds with formation of Me2Si(Nt-Bu)2Ge(TeEt)27, which slowly converts into the Te-bridged complex [Me2Si(Nt-Bu)2GeTe]28. 1–6 and 8 were characterized by single crystal X-ray diffraction.

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Steiniger, P., Bendt, G., Bläser, D., Wölper, C., Schulz, S., 2014. Germane vs. digermane formation. https://doi.org/10.1039/C4CC07921C
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