Syntheses and Solid State Structures of Et2SbTeEt and Et2BiTeEt

Diethylstibanyl‐ and diethylbismuthanyl telluranes Et2MTeEt (M = Sb 1, Bi 2) as well as tBu3Sb (3) were structurally characterized by single‐crystal X‐ray diffraction. Single crystals of 13 were grown by using an IR‐laser‐assisted technique. Compounds 1 and 2 form short intermolecular E···Te interactions in the solid state, which were further investigated with dispersion‐corrected density functional theory.


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