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  • Solid-State Structures of Trialkylbismuthines BiR3 (R = Me, i-Pr)

Solid-State Structures of Trialkylbismuthines BiR3 (R = Me, i-Pr)

Two trialkylbismuthines BiR3 (R = Me (1), i-Pr (2)) were structurally characterized by single-crystal X-ray diffraction. Single crystals were grown using an IR-laser-assisted technique. 1 forms short intermolecular Bi···Bi interactions in the solid state, which were further investigated through quantum chemical computations with ab initio coupled cluster and dispersion-corrected density functional methods.

Dedicated to Prof. Gerald Henkel on the occasion of his 65th birthday.

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Date Issued:
16.11.2020
URN:
urn:nbn:de:hbz:464-20201116-111846-5
DOI:
10.1021/om400730r
Language:
English
Type of Resource:
Text
Keywords:
Bismuth; Crystal Structure; Laser-Assisted Crystallization; Intermolecular Interactions
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Hosting institution:
Faculty of Chemistry, Organische Chemie
Info on primary publication:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Organometallics 2013, 32, 19, 5445–5450, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:
https://doi.org/10.1021/om400730r

Published online 24 September 2013

version identification:
Authors Accepted Manuscript.

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