Solid-State Structures of Trialkylbismuthines BiR3 (R = Me, i-Pr)

Two trialkylbismuthines BiR3 (R = Me (1), i-Pr (2)) were structurally characterized by single-crystal X-ray diffraction. Single crystals were grown using an IR-laser-assisted technique. 1 forms short intermolecular Bi···Bi interactions in the solid state, which were further investigated through quantum chemical computations with ab initio coupled cluster and dispersion-corrected density functional methods.

Dedicated to Prof. Gerald Henkel on the occasion of his 65th birthday.


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