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Syntheses and Solid State Structures of Bis(dialkylstibanyl)Sulfanes and Telluranes

Distibines Sb2R4 (R = Me, Et) react with elemental chalcogens (E = S, Se, Te) with insertion into the Sb–Sb bond and formation of the corresponding bis(dialkylstibanyl)sulfanes, ‐selenanes, and ‐telluranes (R2Sb)2E. The structures of (Et2Sb)2S (1), (Et2Sb)2Te (3), and (Me2Sb)2Te (4) were determined by single‐crystal X‐ray diffraction. The complexes either adopt a syn–syn (1, 4) or syn–anti conformation (3) in the solid state. In addition, the compounds have different intermolecular interaction modes, which depend on the bridging chalcogen and the organic substituent bound to the Sb atoms.

Dedicated to Prof. Werner Uhl on the occasion of his 60th birthday.

 

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Einordnung

alternativ:
Syntheses and Solid‐State Structures of Bis(dialkylstibanyl)sulfanes and ‐telluranes
Datum der Veröffentlichung:
16.11.2020
URN:
urn:nbn:de:hbz:464-20201116-110328-3
DOI:
10.1002/ejic.201300767
Sprache:
Englisch
Ressourcentyp:
Text
Schlagwörter:
Antimony; Laser-Assisted Crystallization; Intermolecular Interactions
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This is the peer reviewed version of the following article: Eur. J. Inorg. Chem. 2013, 28 4909-4915, which has been published in final form at:
https://doi.org/10.1002/ejic.201300767

Version of Record online: 13 August 2013

Restriktion:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Versionskennzeichen:
Authors Accepted Manuscript.

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