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Syntheses and Solid State Structures of Bis(dialkylstibanyl)Sulfanes and Telluranes

Distibines Sb2R4 (R = Me, Et) react with elemental chalcogens (E = S, Se, Te) with insertion into the Sb–Sb bond and formation of the corresponding bis(dialkylstibanyl)sulfanes, ‐selenanes, and ‐telluranes (R2Sb)2E. The structures of (Et2Sb)2S (1), (Et2Sb)2Te (3), and (Me2Sb)2Te (4) were determined by single‐crystal X‐ray diffraction. The complexes either adopt a syn–syn (1, 4) or syn–anti conformation (3) in the solid state. In addition, the compounds have different intermolecular interaction modes, which depend on the bridging chalcogen and the organic substituent bound to the Sb atoms.

Dedicated to Prof. Werner Uhl on the occasion of his 60th birthday.

 

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alternative:
Syntheses and Solid‐State Structures of Bis(dialkylstibanyl)sulfanes and ‐telluranes
Date Issued:
16.11.2020
URN:
urn:nbn:de:hbz:464-20201116-110328-3
DOI:
10.1002/ejic.201300767
Language:
English
Type of Resource:
Text
Keywords:
Antimony; Laser-Assisted Crystallization; Intermolecular Interactions
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Info on primary publication:

This is the peer reviewed version of the following article: Eur. J. Inorg. Chem. 2013, 28 4909-4915, which has been published in final form at:
https://doi.org/10.1002/ejic.201300767

Version of Record online: 13 August 2013

restriction:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
version identification:
Authors Accepted Manuscript.

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