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  • The Origin of Thermochromic Behaviour in Distibines – Still an open Question

The Origin of Thermochromic Behaviour in Distibines – Still an open Question

A detailed structural investigation of Sb2Et4 using an in situ crystallization technique clearly shows that thermochromic behavior of distibines cannot be solely attributed to the formation of intermolecular Sb···Sb interactions in the solid state. Both the yellow and the red phase of Sb2Et4 showed almost identical bond lengths and angles including rather short intermolecular Sb···Sb bond distances.

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Einordnung

Datum der Veröffentlichung:
16.11.2020
URN:
urn:nbn:de:hbz:464-20201116-105752-8
DOI:
10.1021/om4003413
Sprache:
Englisch
Ressourcentyp:
Text
Schlagwörter:
Distibine; Laser-Assisted Crystallization; Intermolecular Interactions; Thermochromicity
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Organometallics 2013, 32, 11, 3391–3394, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:
https://doi.org/10.1021/om4003413

Published online 17 May 2013

Versionskennzeichen:
Authors Accepted Manuscript.

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