Structural Characterization of Amidinatobismuth(III) Diazides

Amidinatobismuth(III) diazides LBi(N3)2 {L1 = [tBuC(NiPr)2] (2), L2 = [tBuC(NDipp)2] (3, Dipp = 2,6‐iPr2‐C6H3)} were synthesized in high yields by metathesis reactions of the corresponding halide‐substituted complexes L1BiI2 (1) and L2BiCl2 with AgN3. Compounds 1–3 were characterized by using elemental analyses, multinuclear NMR (1H, 13C), and IR spectroscopy as well as by using single‐crystal X‐ray diffraction (for 2, 3).

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Date Issued:
12.11.2020
URN:
urn:nbn:de:hbz:464-20201112-093420-3
DOI:
10.1002/ejic.201200699
Language:
English
Type of Resource:
Text
Keywords:
Bismuth; Amidinate; Azide; X-ray diffraction
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Hosting institution:
Faculty of Chemistry, Organische Chemie
Info on primary publication:

This is the peer reviewed version of the following article: Eur. J. Inorg. Chem. 2012, 27, 4350-4355, which has been published in final form at:
https://doi.org/10.1002/ejic.201200699

Version of Record online: 17 August 2012

restriction:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
version identification:
Authors Accepted Manuscript.

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