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  • First structural characterization of neutral, base-stabilized group 15-pentaazides…

First structural characterization of neutral, base-stabilized group 15-pentaazides - single crystal X-ray structures of dmap-As(N3)5 and dmap-Sb(N3)5.

Two neutral group 15-pentaazides dmap-As(N(3))(5) (1) and dmap-Sb(N(3))(5) (2) were synthesized and structurally characterized for the first time (dmap = 4-dimethylaminopyridine). Base-stabilization was confirmed to be very suitable for the kinetic stabilization of highly explosive covalent main group polyazides.

Dedicated to Prof. Dr. H. Willner on the occasion of his 65th birthday.

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Date Issued:
12.11.2020
URN:
urn:nbn:de:hbz:464-20201112-090807-8
DOI:
10.1021/ic300523k
Language:
English
Type of Resource:
Text
Keywords:
Covalent Azide; X-ray diffraction; DFT Computations
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Hosting institution:
Faculty of Chemistry, Organische Chemie
Info on primary publication:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Inorg. Chem. 2012, 51, 10, 5897–5902, copyright © American Chemical Society after peer review and technical editing by the publisher.

To access the final edited and published work see:
https://doi.org/10.1021/ic300523k

Published online 30 April 2012

version identification:
Authors Accepted Manuscript.

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