First structural characterization of neutral, base-stabilized group 15-pentaazides - single crystal X-ray structures of dmap-As(N3)5 and dmap-Sb(N3)5.

Two neutral group 15-pentaazides dmap-As(N(3))(5) (1) and dmap-Sb(N(3))(5) (2) were synthesized and structurally characterized for the first time (dmap = 4-dimethylaminopyridine). Base-stabilization was confirmed to be very suitable for the kinetic stabilization of highly explosive covalent main group polyazides.

Dedicated to Prof. Dr. H. Willner on the occasion of his 65th birthday.


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