First structural characterization of neutral, base-stabilized group 15-pentaazides - single crystal X-ray structures of dmap-As(N3)5 and dmap-Sb(N3)5.

Lyhs, Benjamin GND; Bläser, Dieter; Wölper, Christoph GND; Schulz, Stephan GND; Jansen, Georg LSF

Two neutral group 15-pentaazides dmap-As(N(3))(5) (1) and dmap-Sb(N(3))(5) (2) were synthesized and structurally characterized for the first time (dmap = 4-dimethylaminopyridine). Base-stabilization was confirmed to be very suitable for the kinetic stabilization of highly explosive covalent main group polyazides.

Dedicated to Prof. Dr. H. Willner on the occasion of his 65th birthday.

Cite

Citation style:
Lyhs, B., Bläser, D., Wölper, C., Schulz, S., Jansen, G., 2020. First structural characterization of neutral, base-stabilized group 15-pentaazides - single crystal X-ray structures of dmap-As(N3)5 and dmap-Sb(N3)5. https://doi.org/10.1021/ic300523k
Could not load citation form.

Rights

Use and reproduction:
All rights reserved

Export