Insertion Reactions of Heterocumulenes with Zincocene Cp*2Zn

Zincocene Cp*2Zn reacts with carbodiimides C(NR)2 with insertion into the Zn–Cp* bond and formation of [(Cp*C(NR)2]2Zn [R = Et (1), iPr (2), Cy (3)]. In addition, the reaction of Cp*2Zn with CS2 under dry conditions gives (Cp*CS2)2Zn (4), whereas in the presence of a small amount of water [Zn4(μ4‐O)(S2CCp*)6] (5) is obtained. Compounds 1–4 were characterized by NMR (1H, 13C) and IR spectroscopy as well as elemental analysis and single‐crystal X‐ray diffraction (2–4, 5 of poor quality). The solid‐state structure of 5 is comparable to the carboxylate complex previously obtained from the reaction of Cp*2Zn with CO2.

Dedicated to Prof. K. Jurkschat on the Occasion of his 60th Birthday.

Preview

Category

Date Issued:
12.11.2020
URN:
urn:nbn:de:hbz:464-20201112-101351-1
DOI:
10.1002/zaac.201200061
Language:
English
Type of Resource:
Text
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Info on primary publication:

This is the peer reviewed version of the following article: Z. Anorg. Allg . Chem. 2012, 638,1705-1710, which has been published in final form at:
https://doi.org/10.1002/zaac.201200061

Version of Record online: 26 April 2012

restriction:
This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
version identification:
Authors Accepted Manuscript.

Cite

Citation style:
Could not load citation form.

Rights

Use and reproduction:
All rights reserved