Structural characterization of Sb2Et4 and Bi2Et4

The solid state structures of Et4Sb2 1 and Et4Bi2 2 were determined by single crystal Xray diffraction. Single crystals of 1 and 2 were grown in a closed quartz glass capillary under an inert argon atmosphere on the diffractometer using a specific IR-laser-assisted technique. 1 shows short intermolecular Sb···Sb interactions, whereas the closest Bi···Bi distances are longer than the sum of the van-der-Waals radii.

Vorschau

Einordnung

alternativ:
Structural Characterization of Et4Sb2 and Et4Bi2
Datum der Veröffentlichung:
10.11.2020
URN:
urn:nbn:de:hbz:464-20201110-151607-0
DOI:
10.1021/om2005723
Sprache:
Englisch
Ressourcentyp:
Text
Schlagwörter:
Dibismuthine; Distibine; Thermochromism; X-Ray Crystal structure
Kollektion:
E-Publikationen
Sachgruppen der Deutschen Nationalbibliographie:
540 Chemie
Einrichtung:
Fakultät für Chemie, Anorganische Chemie
Informationen zur Erstveröffentlichung:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Organometallics 2011, 30, 17, 4730–4735, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:
https://doi.org/10.1021/om2005723

Published online 5 August 2011

 

Versionskennzeichen:
Authors Accepted Manuscript.

Zitieren

Zitierform:
Zitierform konnte nicht geladen werden.

Rechte

Nutzung und Vervielfältigung:
Alle Rechte vorbehalten