Structural characterization of Sb2Et4 and Bi2Et4

The solid state structures of Et4Sb2 1 and Et4Bi2 2 were determined by single crystal Xray diffraction. Single crystals of 1 and 2 were grown in a closed quartz glass capillary under an inert argon atmosphere on the diffractometer using a specific IR-laser-assisted technique. 1 shows short intermolecular Sb···Sb interactions, whereas the closest Bi···Bi distances are longer than the sum of the van-der-Waals radii.

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alternative:
Structural Characterization of Et4Sb2 and Et4Bi2
Date Issued:
10.11.2020
URN:
urn:nbn:de:hbz:464-20201110-151607-0
DOI:
10.1021/om2005723
Language:
English
Type of Resource:
Text
Keywords:
Dibismuthine; Distibine; Thermochromism; X-Ray Crystal structure
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Info on primary publication:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Organometallics 2011, 30, 17, 4730–4735, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:
https://doi.org/10.1021/om2005723

Published online 5 August 2011

 

version identification:
Authors Accepted Manuscript.

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