Syntheses and structures of triazides of heavy group 15 elements

Synthesis of group 15-triazides E(N3)3 (E = Sb 1, Bi 2) and Py2–Bi(N3)33 (Py = pyridine). Single crystals of 1 were in situ grown by an IR-laser-assisted technique on the diffractometer. The structure of 3, which represents the first structurally characterized neutral Bi-triazide, is influenced by crystal packing effects according to DFT calculations.

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