Syntheses and structures of triazides of heavy group 15 elements

Schulz, Stephan GND; Lyhs, Benjamin GND; Jansen, Georg LSF; Bläser, Dieter; Wölper, Christoph GND

Synthesis of group 15-triazides E(N3)3 (E = Sb 1, Bi 2) and Py2–Bi(N3)33 (Py = pyridine). Single crystals of 1 were in situ grown by an IR-laser-assisted technique on the diffractometer. The structure of 3, which represents the first structurally characterized neutral Bi-triazide, is influenced by crystal packing effects according to DFT calculations.

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Schulz, S., Lyhs, B., Jansen, G., Bläser, D., Wölper, C., 2020. Syntheses and structures of triazides of heavy group 15 elements. https://doi.org/10.1039/C1CC10237K
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