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Synthesis and Structural Characterization of New Zinc Amidinate Complexes

The synthesis and reactivity of heteroleptic zinc complexes of the type LZnX (X = Me, I) containing amidinate ligands L of varying steric bulk were investigated. Complexes of the type LZnMe, which were obtained from the homoleptic complexes L2Zn upon reaction with ZnMe2, react with iodine with subsequent formation of LZnI. Single-crystal X-ray structures of the amidinate zinc complexes [{MeC(Ni-Pr)2}ZnMe]2, 1, [{MeC(Ni-Pr)2}ZnI]2LiI(OEt)2, 3, [t-BuC(NDipp)2]ZnMe, 5, [t-BuC(NDipp)2]ZnMe(t-BuPy), 6, [{t-BuC(NDipp)2}Zn(μ-I)]2, 7, and [t-BuC{N(H)Dipp}2][Al{OC(CF3)3}4], 8, are reported.

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Date Issued:
04.11.2020
URN:
urn:nbn:de:hbz:464-20201104-102845-5
DOI:
10.1021/om1008549
Language:
English
Type of Resource:
Text
Keywords:
Hydrocarbons; Reaction mechanisms; Zinc; Ligands; Crystal structure
Collection:
E-Publications
Subject categories of the Deutsche Nationalbibliografie:
540 Chemistry & allied sciences
Hosting institution:
Faculty of Chemistry, Anorganische Chemie
Info on primary publication:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Organometallics 2010, 29, 22, 6097–6103, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:

https://doi.org/10.1021/om1008549

Published online 28 October 2010

 

version identification:
Authors Accepted Manuscript.

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