Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex

Gutschank, Benjamin; Schulz, Stephan; Bläser, Dieter; Boese, Roland; Wölper, Christoph

doi:10.1021/om100966d

Veröffentlicht

Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex

Gutschank, Benjamin ; Schulz, Stephan ; Bläser, Dieter; Boese, Roland ; Wölper, Christoph

The tetranuclear amidinato zinc hydride complex {C[C(Ni-Pr)₂ZnH]₄} (3) was synthesized by reaction of the Cl-substituted complex {C[C(Ni-Pr)₂ZnCl]₄} with CaH₂. 3 was found to react with phenylacetylene and acetylene at ambient temperature with elimination of H₂ and subsequent formation of C[C(Ni-Pr)₂ZnC≡CPh]₄ (4) and {C[C(Ni-Pr)₂ZnC≡CH]₄ (5), respectively. 3−5 have been characterized by multinuclear NMR (¹H, ¹³C) and IR spectroscopy, elemental analyses, and single-crystal X-ray diffraction.

Vorschau

/Accepted_Manuscript_Organometallics_2010_29_6133.pdf

Einordnung

Datum der Veröffentlichung:

04.11.2020

URN:

urn:nbn:de:hbz:464-20201104-101948-8

DOI:

10.1021/om100966d

Sprache:

Englisch

Ressourcentyp:

Text

Schlagwörter:

Hydrides; Acetylides; Zinc; X-Ray Diffraction

Kollektion:

E-Publikationen

Sachgruppen der Deutschen Nationalbibliographie:

540 Chemie

Einrichtung:

Fakultät für Chemie, Anorganische Chemie

Informationen zur Erstveröffentlichung:

This document is the Accepted Manuscript version of a Published Work that appeared in final form in: Organometallics 2010, 29, 22, 6133–6136, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see:

https://doi.org/10.1021/om100966d

Published online 22 October 2010

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