Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex

Gutschank, Benjamin GND; Schulz, Stephan GND; Bläser, Dieter; Boese, Roland GND; Wölper, Christoph GND

The tetranuclear amidinato zinc hydride complex {C[C(Ni-Pr)2ZnH]4} (3) was synthesized by reaction of the Cl-substituted complex {C[C(Ni-Pr)2ZnCl]4} with CaH2. 3 was found to react with phenylacetylene and acetylene at ambient temperature with elimination of H2 and subsequent formation of C[C(Ni-Pr)2ZnC≡CPh]4 (4) and {C[C(Ni-Pr)2ZnC≡CH]4 (5), respectively. 35 have been characterized by multinuclear NMR (1H, 13C) and IR spectroscopy, elemental analyses, and single-crystal X-ray diffraction.

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Gutschank, B., Schulz, S., Bläser, D., Boese, R., Wölper, C., 2020. Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex. https://doi.org/10.1021/om100966d
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