Solid-state and Solution Studies on a β-Diketiminate Zinc Hydride Complex

Schulz, Stephan GND; Eisenmann, Tamara GND; Schuchmann, Daniella GND; Bolte, Michael ORCID; Kirchner, Michael; Boese, Roland GND; Spielmann, Jan GND; Harder, Sjoerd GND

[MesnacnacZn(μ-H)]2 (1) was synthesized by reaction of MesnacnacZnI with either an equimolar amount of KNH(iPr)BH3 or an excess of NaH and characterized by multinuclear NMR and IR spectroscopy as well as X-ray diffraction. Two polymorphs of 1 were found and their structures determined on single crystals.

Dedicated to Professor Hubert Schmidbaur on the occasion of his 75th birthday.

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Schulz, S., Eisenmann, T., Schuchmann, D., Bolte, M., Kirchner, M., Boese, R., Spielmann, J., Harder, S., 2014. Solid-state and Solution Studies on a β-Diketiminate Zinc Hydride Complex. https://doi.org/10.1515/znb-2009-11-1221
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