Zinc Carbodiimide Cluster Complexes – Synthesis, XRay Crystal Structures and Reaction Mechanism

Schmidt, Sarah GND; Gondzik, Sebastian GND; Schulz, Stephan GND; Bläser, Dieter; Boese, Roland GND

Reactions of Me2Zn with carbodiimides C(NR)2 in different molar ratios at elevated temperature were investigated, a possible reaction mechanism was identified, and the single-crystal X-ray structures of polynuclear amidinate zinc complexes {C[C(NCy)2ZnMe]4}, 1, {C[C(NCy)2ZnMe]3(ZnMe)}, 3, and {C[C(NCy)2ZnMe]3(ZnMe)(MeZnOMe)}, 5, are reported.

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Schmidt, S., Gondzik, S., Schulz, S., Bläser, D., Boese, R., 2020. Zinc Carbodiimide Cluster Complexes – Synthesis, XRay Crystal Structures and Reaction Mechanism. https://doi.org/10.1021/om900373p
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