@Article{duepublico_mods_00073215, author = {Schulz, Stephan and Fl{\"o}rke, Ulrich}, title = {Base-stabilized dimeric organozinc alkoxides}, year = {2020}, month = {Nov}, day = {04}, keywords = {Base-stabilized organozinc alkoxide}, abstract = {Dimeric, base-stabilized organozinc alkoxides [dmap-Zn(R)$\mu$-OR]2 (R = Et 1; i-Pr 2), were obtained from reactions of ZnR2 and 4-dimethylaminopyridine (dmap) in the presence of O2. Their solid state structures were determined by single crystal X-ray diffraction studies. 1 is triclinic, space group P-1 with a = 8.0639(10) {\AA}, b = 8.3082(11) {\AA}, c = 10.4545(13) {\AA}, $\alpha$ = 70.846(2){\textdegree}, $\beta$ = 72.316(2){\textdegree}, $\gamma$ = 81.505(2){\textdegree} and Z = 1. 2 is triclinic, space group P-1 with a = 8.6381(6) {\AA}, b = 9.2773(7) {\AA}, c = 10.2186(7) {\AA}, $\alpha$ = 112.094(1){\textdegree}, $\beta$ = 103.040(1){\textdegree}, $\gamma$ = 92.598(1){\textdegree} and Z = 1.}, note = {<p>This is a post-peer-review, pre-copyedit version of an article published in: J Chem Crystallogr, 40, 888--891(2010). The final authenticated version is available online at: <a href="https://doi.org/10.1007/s10870-010-9843-2">https://doi.org/10.1007/s10870-010-9843-2</a></p> <p>Published: 17 July 2010</p>}, note = {Authors Accepted Manuscript}, doi = {10.1007/s10870-010-9843-2}, url = {https://duepublico2.uni-due.de/receive/duepublico_mods_00073215}, url = {https://doi.org/10.1007/s10870-010-9843-2}, file = {:https://duepublico2.uni-due.de/servlets/MCRFileNodeServlet/duepublico_derivate_00073023/Accepted_Manuscript_JChemCrystallogr_2010_40_888.pdf:PDF}, language = {en} }