@Article{duepublico_mods_00048899, author = {Pint, Bruce A. and Unocic, Kinga A. and Keiser, James R. and {3rd European supercritical CO2 Conference September 19-20, 2019, Paris, France}}, editor = {Brillert, Dieter}, title = {Effect of impurities on supercritical CO2 compatibility}, journal = {3rd European Conference on Supercritical CO2 (sCO2) Power Systems 2019: 19th-20th September 2019}, year = {2019}, month = {Oct}, day = {07}, pages = {238--244}, abstract = {Impurities may affect structural alloy compatibility in both indirect- and direct-fired supercritical CO2 (sCO2) cycles for high efficiency power generation with peak temperatures above 700{\textdegree}C. Using a new multi-pump gas control system, experiments with controlled impurity additions were compared to baseline results in research- or industrial-grade CO2 at 750{\textdegree}C/300 bar. Low level impurities, 50 ppm O2 and 50 ppm H2O, were not found to affect mass change or reaction products after 2,500 h exposures. However, in RG sCO2+1{\%}O2+0.25{\%}H2O, higher reaction rates were observed for both Ni- and Fe-based alloys, but especially Fe-based alloys were strongly affected by these high impurity levels. Analytical TEM was used to characterize the reaction products on alloy 625.}, note = {142}, issn = {2510-7852}, doi = {10.17185/duepublico/48899}, url = {https://duepublico2.uni-due.de/receive/duepublico_mods_00048899}, url = {https://doi.org/10.17185/duepublico/48899}, url = {https://doi.org/10.17185/duepublico/48871}, url = {https://doi.org/10.17185/duepublico/48870}, file = {:https://duepublico2.uni-due.de/servlets/MCRFileNodeServlet/duepublico_derivate_00070577/Pint_et_al_Effect_of_impurities.pdf:PDF}, language = {en} }